Catalytic Rearrangement of Four Substituted Tetrahydropyridine

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Аннотация

A new compound, 5-acetyl-2-amino-4-(2-chloro-5-nitrophenyl)-6-oxo-1-phenyl-1,4,5,6-tetrahydropyridine-3-carbonitrile, was synthesized by the reaction of 2-chloro-5-nitrobenzylidenemalononitrile with malononitrile and aniline. Subsequently, it was subjected to catalytic rearrangement in the presence of ethylenediamine and a second new compound, 4-(2-chloro-5-nitrophenyl)-6-oxo-2-(phenylamino)-1,4,5,6-tetrahydropyridine-3-carbonitrile, was obtained. The structure of the products was determined using NMR spectroscopy and X-ray diffraction analysis. A probable mechanism of the rearrangement reaction was proposed.

Авторлар туралы

F. Naghiyev

Baku State University

ORCID iD: 0009-0003-9325-1756
Baku, Azerbaijan

V. Khrustal'ev

Peoples' Friendship University of Russia (RUDN University); N.D. Zelinsky Institute of Organic Chemistry RAS

ORCID iD: 0000-0001-8806-2975
Moscow, Russia; Moscow, Russia

M. Komarovskikh

Peoples' Friendship University of Russia (RUDN University)

ORCID iD: 0009-0004-6733-2322
Moscow, Russia

M. Tachaev

Peoples' Friendship University of Russia (RUDN University)

ORCID iD: 0000-0003-3606-0868
Moscow, Russia

I. Mamedov

Baku State University

Email: bsu.mmrtab@gmail.com
ORCID iD: 0000-0002-5757-9899
Baku, Azerbaijan

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