Unexpected Product of Allyl Hydroxylation During Ozone Degradation of  N -Tosylate 2-(Cyclohex-1-en-1-yl)-6-methylaniline

Rail R. Safargalin; Сафаргалин Раиль Рафаэлевич; Rail R. Gataullin; Гатауллин Раил Рафкатович

doi:10.31857/S0514749225040043

Unexpected Product of Allyl Hydroxylation During Ozone Degradation of N-Tosylate 2-(Cyclohex-1-en-1-yl)-6-methylaniline

作者: Safargalin R.R.¹, Gataullin R.R.¹
隶属关系:
1. Ufa Institute of Chemistry of the Ufa Federal Research Center of the RAS
期: 卷 61, 编号 4 (2025)
页面: 387-392
栏目: ЭКСПЕРИМЕНТАЛЬНЫЕ СТАТЬИ
URL: https://stomuniver.ru/0514-7492/article/view/689615
DOI: https://doi.org/10.31857/S0514749225040043
EDN: https://elibrary.ru/SDHLIF
ID: 689615

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详细

During the ozonolysis of N-[(2-cyclohex-1-en-1-yl)-6-methylphenyl]-4-methylbenzenesulfonamide followed by the reduction of oxidation products with dimethyl sulfide, the expected ketoaldehyde—4-methyl-N-[2-methyl-6-(6-oxohexanoyl)phenyl]benzenesulfonamide—is formed, along with an unexpected allyl hydroxylation product—N-[2-(6-hydroxycyclohex-1-en-1-yl)-6-methylphenyl]-4-methylbenzenesulfonamide.

关键词

ozonolysis, toluenesulfonamide, allyl hydroxylation, molozonide

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作者简介

Rail Safargalin

Ufa Institute of Chemistry of the Ufa Federal Research Center of the RAS

编辑信件的主要联系方式.
Email: gataullin@anrb.ru
ORCID iD: 0009-0007-9462-9027
俄罗斯联邦, 71, Oktyabr Ave., Ufa, 450054

Rail Gataullin

Ufa Institute of Chemistry of the Ufa Federal Research Center of the RAS

Email: gataullin@anrb.ru
ORCID iD: 0000-0003-3269-2729
俄罗斯联邦, 71, Oktyabr Ave., Ufa, 450054

参考

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