Kinetics and Mechanism of Allyl Chloride Epoxidation Using TS-1 as a Catalyst and Hydrogen Peroxide

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The kinetics of allyl chloride epoxidation with hydrogen peroxide at TS-1 catalyst has been studied. The kinetic data analysis allowed us to exclude only a part of the hypotheses about the mechanism, which were formulated on the basis of the available physico-chemical information about the structure of the TS-1 active center. The characteristics of the allyl chloride epoxidation process were compared with the characteristics of allyl alcohol epoxidation. In order to adequately describe the experimental data, it is necessary to take into account the strong binding of the active sites of the catalyst with hydrogen peroxide and epichlorohydrin. The Eley–Rideal type mechanism is recognized as an adequate kinetic model. Additional physico-chemical or computational data are needed to further discriminate the remaining hypotheses. Another way is to use additional information about the kinetics of by–products formation.

 

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作者简介

Z. Pastukhova

MIREA – Russian Technological University, Lomonosov Institute of Fine Chemical Technologies

编辑信件的主要联系方式.
Email: pastuhova@mirea.ru
俄罗斯联邦, 86 Vernadsky Ave., Moscow, 119571

Е. Katsman

MIREA – Russian Technological University, Lomonosov Institute of Fine Chemical Technologies

Email: pastuhova@mirea.ru
俄罗斯联邦, 86 Vernadsky Ave., Moscow, 119571

L. Bruk

MIREA – Russian Technological University, Lomonosov Institute of Fine Chemical Technologies

Email: pastuhova@mirea.ru
俄罗斯联邦, 86 Vernadsky Ave., Moscow, 119571

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2. Scheme 1

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3. Fig. 1. Kinetic curves of changes in the concentration of allyl chloride (AC) and epichlorohydrin (ECH) (a) and UK peroxide (b) during the course of the state.

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4. Fig. 2. Dependence of the rate of formation of epichlorohydrin on temperature (С0АХ = 2.38 mol/l; С0ПВ = 2.38 mol/l).

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5. Fig. 3. The effect of changing the initial concentration of allyl chloride on its current concentration (a) and on the formation of epichlorohydrin (b) (С0ПВ = 2.38 mol/l).

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6. Fig. 4. The effect of changing the initial concentration of hydrogen peroxide on its current concentration (a) and on the formation of epichlorohydrin (b) (С0АХ = 2.37 mol/l).

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7. Fig. 5. The effect of adding epichlorohydrin to the initial mixture on the consumption of allyl chloride and the formation of epichlorohydrin (a), on the consumption of hydrogen peroxide (b) (С0АХ = 2.35 mol/l; С0ПВ = 2.37 mol/l).

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8. Fig. 6. Effect of water concentration on the formation of epichlorohydrin (С0АХ = 1.00 mol/l; С0ПВ = 1.00 mol/l; С0H2O = 4.12 mol/l; 0.00 mol/l – no additional water was added to the system, the water concentration at the initial moment of time was equal to С0H2O; 3.99 mol/l – 3.99 mol/l of water was added to С0H2O; 8.20 mol/l – 8.20 mol/l of water was added to С0H2O).

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9. Fig. 7. Correspondence between the calculated according to model 8 and the experimentally obtained concentrations of hydrogen peroxide for all experiments (the epoxidation reaction of allyl chloride).

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10. Scheme

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11. Scheme 2

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12. Scheme 1. Hydroperoxide mechanism of epoxidation on titanium-containing catalysts.

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13. Scheme 2. Proposed mechanism (Eley–Rideal model) for the epoxidation of allyl chloride on catalyst TS-1 (a fragment of the catalyst structure is shown, including the active center and associated groups).

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