Studying the Properties of Molecular Sites Produced from Gels Containing Layered 2D Silicoalumophosphates with Different SiO 2 /Al 2 O 3  Ratio

M. R. Agliullin; Аглиуллин М. Р.; D. V. Serebrennikov; Серебренников Д. В.; L. M. Khalilov; Халилов Л. М.; Z. R. Fayzullina; Файзуллина З. Р.; I. N. Pavlova; Павлова И. Н.; B. I. Kutepov; Кутепов Б. И.

doi:10.31857/S0453881123030012

Studying the Properties of Molecular Sites Produced from Gels Containing Layered 2D Silicoalumophosphates with Different SiO₂/Al₂O₃ Ratio

Authors: Agliullin M.R.¹, Serebrennikov D.V.¹, Khalilov L.M.¹, Fayzullina Z.R.², Pavlova I.N.¹, Kutepov B.I.²
Affiliations:
1. Institute of Petrochemistry and Catalysis Ufa Federal Research Centre of the Russian Academy of Sciences
2. Ufa State Petroleum Technological University
Issue: Vol 64, No 3 (2023)
Pages: 326-335
Section: ARTICLES
URL: https://stomuniver.ru/0453-8811/article/view/660299
DOI: https://doi.org/10.31857/S0453881123030012
ID: 660299

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Abstract

Abstract—

Crystallization of molecular SAPO-41 sieves from gels containing layered 2D silicoaluminophosphates with various SiO₂/Al₂O₃ molar ratios (from 0.1 to 0.3). The effect of the presence of layered phases in gels on the chemical and phase composition, acid properties, and the characteristics of the porous structure of their crystallization products has been established. A method for the synthesis of SAPO-41 of high phase purity and degree of crystallinity is proposed. The catalytic properties in the hydromeasurement of n-hexadecane prepared on the basis of the obtained molecular sieves of Pt-containing catalytic systems have been studied.

Keywords

silicoaluminophosphates, gels, crystallization, SAPO-41

References

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