The Study of Catalysis Mechanism in “Copper- and Ligand-Free” Sonogashira Reaction Using the Analysis of Phase Trajectories

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The results are presented on the comparative studies of the differential selectivity patterns in “copper- and ligand-free” Sonogashira reaction under so-called artificial multiroutness aimed at the distinguishing between homogeneous and heterogeneous catalysis mechanisms. Using various amounts of soluble and insoluble heterogeneous catalyst precursors resulted in the same values of the differential selectivity of competing aryl iodides, of arylacetylenes, or of the reaction products. The observed patterns conform to the hypothesis about Sonogashira reaction proceeding through homogeneous catalysis mechanism even when heterogeneous insoluble catalyst precursors are used.

Авторлар туралы

E. Larina

Irkutsk State University, Chemical Department

Email: aschmidt@chem.isu.ru
Russia, 664003, Irkutsk, K. Marx str., 1

A. Kurokhtina

Irkutsk State University, Chemical Department

Email: aschmidt@chem.isu.ru
Russia, 664003, Irkutsk, K. Marx str., 1

N. Lagoda

Irkutsk State University, Chemical Department

Email: aschmidt@chem.isu.ru
Russia, 664003, Irkutsk, K. Marx str., 1

T. Grigoryeva

Irkutsk State University, Chemical Department

Email: aschmidt@chem.isu.ru
Russia, 664003, Irkutsk, K. Marx str., 1

A. Schmidt

Irkutsk State University, Chemical Department

Хат алмасуға жауапты Автор.
Email: aschmidt@chem.isu.ru
Russia, 664003, Irkutsk, K. Marx str., 1

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