New Barium Fluorosuccinato and Fluoroglutarato Uranylates

V. N. Serezhkin; Сережкин В. Н.; M. S. Grigoriev; Григорьев М. С.; M. V. Sukacheva; Сукачева М. В.; L. B. Serezhkina; Сережкина Л. Б.

doi:10.31857/S0044453723040283

New Barium Fluorosuccinato and Fluoroglutarato Uranylates

Authors: Serezhkin V.N.¹, Grigoriev M.S.², Sukacheva M.V.¹, Serezhkina L.B.¹
Affiliations:
1. Samara National Research University
2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Issue: Vol 97, No 4 (2023)
Pages: 535-542
Section: СТРОЕНИЕ ВЕЩЕСТВА И КВАНТОВАЯ ХИМИЯ
Submitted: 27.02.2025
Published: 01.04.2023
URL: https://stomuniver.ru/0044-4537/article/view/668772
DOI: https://doi.org/10.31857/S0044453723040283
EDN: https://elibrary.ru/TIMCCR
ID: 668772

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Two new coordination polymers: Ba2[(UO2)3(suc)3F4]⋅5H2O (I) and Ba[(UO2)2(glt)2(Hglt)F]⋅8H2O (II), where suc is C4H4O2−442− (succinate ion) and glt is C5H6O2−442− (glutarate ion), were synthesized, and their structure was studied. The uranium-containing structural units of crystals I are the [(UO2)3(C4H4O4)3F4]4– layers belonging to the crystal-chemical group A3(Q02)3M22M22M12M21 of uranyl complexes, where A = UO2+2UO22+, Q02 = C4H4O2−442−, М1 and М2 = F–. Structure II contains the uranium-containing 3D complex [(UO2)2(C5H6O4)2(C5H7O4)F]2–, which corresponds to the crystal-chemical formula A2(Q02)2B01M2, where A = UO2+2UO22+, Q02 = C5H6O2−442−, B01 = C5H7O−44−, and М2 = F–.

Keywords

uranyl complexes, succinate ions, glutarate ions, crystal structure, Voronoi–Dirichlet polyhedra

References

Andrews M.B., Cahill C.L. // Chem. Rev. 2013. V. 113. P. 1121. https://doi.org/10.1021/cr300202a
Loiseau T., Mihalcea I., Henry N., Volkringer C. // Coord. Chem. Rev. 2014. V. 266–267. P. 69. https://doi.org/10.1016/j.ccr.2013.08.038
Su J., Chen J. MOFs of Uranium and the Actinides, in: P. Cheng (Ed.), Lanthan. Met.-Org. Framew., Springer Berlin Heidelberg, 2014: P. 265. https://doi.org/10.1007/430_2014_158
Novikov S.A., Grigoriev M.S., Serezhkina L.B., Serezhkin V.N. // J. Solid State Chem. 2017. V. 248. P. 178. https://doi.org/10.1016/j.jssc.2017.02.010
Novikov S.A., Serezhkina L.B., Grigoriev M.S., Serezhkin V.N. // Polyhedron. 2018. V. 141. P. 147. https://doi.org/10.1016/j.poly.2017.11.031
Сережкин В.Н., Пушкин Д.В., Сережкина Л.Б. // Радиохимия. 2022. Т. 64. № 4. С. 359. https://doi.org/10.31857/S0033831122040037
SAINT-Plus (Version 7.68) // Bruker AXS Inc., Madison, Wisconsin, USA. 2007.
Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Cryst. 2015. V. 48. P. 3.
Sheldrick G.M. // Acta Crystallogr. 2008. V. 64A. № 1. P. 112.
Sheldrick G.M. // Ibid. 2015. V. 71C. № 1. P. 3.
Cережкин В.Н., Михайлов Ю.Н., Буслаев Ю.А. // Журн. неорган. химии. 1997. Т. 42. № 12. С. 2036.
Nakamoto K. Infrared and Raman spectra of inorganic and coordination compounds. Part A, B, sixth ed, Wiley, Hoboken, 2009.
Krishnan S., Raj C.J., Robert R. et al. // Cryst. Res. Technol. 2007. V. 42. № 11. P. 1087. https://doi.org/10.1002/crat.200710981
Tarakeshwar P., Manogaran S. // J. Mol. Struct. (Theohem.). 1996. V. 362. P. 77. http: dx.doi.org/.https://doi.org/10.1016/0166-1280(95)04375-6
Serezhkin V.N., Savchenkov A.V., Pushkin D.V., Serezhkina L.B. // Applied solid state chemistry. 2018. № 2. P. 2. https://doi.org/10.18572/2619-0141-2018-2-3-2-16
Serezhkin V.N., Vologzhanina A.V., Serezhkina L.B. et al. // Acta Crystallogr. 2009. V. B65. Part 1. P. 45. https://doi.org/10.1107/S0108768108038846
Сережкин В.Н., Рогалева Е.Ф., Шилова М.Ю. и др. // Журн. физ. химии. 2018. Т. 92. № 8. С. 1289.
Сережкин В.Н., Медведков Я.А., Сережкина Л.Б., Пушкин Д.В. // Журн. физ. химии. 2015. Т. 89. № 6. С. 978.
O’Keeffe M. // Z. Kristall. – Crystall. Mater. 2010. V. 210. P. 905. https://doi.org/10.1524/zkri.1995.210.12.905
Deifel N.P., Holman K.T., Cahill C.L. // Chem. Commun. 2008. № 45. P. 6037. https://doi.org/10.1039/B813819B
Kim J.-Y., Norquist A.J., O’Hare D. // Dalton Trans. 2003. P. 2813.https://doi.org/10.1039/B306733P